Issue 4, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolation of a spin-frustrated imidazolate-bridged trinuclear copper(II) complex potentially relevant to the multicopper oxidases

Phalguni Chaudhuri,   Ina Karpenstein,   Manuela Winter,   Christian Butzlaff,   Eckhard Bill,   Alfred X. Trautwein,   Ulrich Flörke  and  Hans-Jürgen Haupt  

Abstract

The reaction of Cu(MeCO2)2·H2O with 1,4,7-trimethyl-1,4,7-triazacyclononane (L) and imidazole (ImH) in methanol affords, in the presence of a small amount of triethylamine and NaClO4, the blue trinuclear complex [L3Cu3(Im)3](ClO4)3 which has been characterized by X-ray crystallography, EPR and magnetic susceptibility measurements to be a spin-frustrated triangular imidazolate-bridged copper(II) complex without any µ3-X ligand.

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Article information

DOI
https://doi.org/10.1039/C39920000321
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 321-322

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Isolation of a spin-frustrated imidazolate-bridged trinuclear copper(II) complex potentially relevant to the multicopper oxidases

P. Chaudhuri, I. Karpenstein, M. Winter, C. Butzlaff, E. Bill, A. X. Trautwein, U. Flörke and H. Haupt, J. Chem. Soc., Chem. Commun., 1992, 321 DOI: 10.1039/C39920000321

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