Issue 1, 1992

Reactivity of [{Y(C5Me5)(OC6H3But2)(µ-H)}2] with terminal alkene and alkynes: a model for the first insertion step in alkene polymerization

Abstract

Terminal alkenes H2C[double bond, length half m-dash]CHR (R = H, Me, Bun) react with [{Y(C5Me5)(OAr)(µ-H)}2]1 to give the µ-n-alkyl species trans-[{Y(C5Me5)(OAr)}2(µ-H)(µ-CH2 CH2R)](R = H 2, Me 3, Bun4), respectively; HC[triple bond, length half m-dash]CSiMe3 reacts to give [{Y(C5Me5)(OAr)}2(µ-H)(µ-C[triple bond, length half m-dash]CSiMe3)]5.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 11-13

Reactivity of [{Y(C5Me5)(OC6H3But2)(µ-H)}2] with terminal alkene and alkynes: a model for the first insertion step in alkene polymerization

C. J. Schaverien, J. Chem. Soc., Chem. Commun., 1992, 11 DOI: 10.1039/C39920000011

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