The pyridinium betaine H5C5N·FPS2 dissociates at 770 K in the gas phase yielding the novel σ3λ5-phosphorane FPS2, which at 900 K splits off S2 to give FPS as substantiated by comparison with the photoelectron spectrum from its generation by Br2FPS debromination on silver wool above 800 K.
H. Bock, M. Kremer, B. Solouki, M. Binnewies and M. Meisel, J. Chem. Soc., Chem. Commun., 1992, 9 DOI: 10.1039/C39920000009
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...