Polybutadiene functionalised with chlorosilyl groups via homogeneous catalytic reactions can be treated with picolyl- or bipyridyl-lithium reagents to give polymer-bound ligands, which will bind metal centres chemically or electrochemically; alternatively, zinc porphyrin units can be bound to the polymer via phenolysis of the Si–Cl bonds.
A. Iraqi, M. Watkinson, J. A. Crayston and D. J. Cole-Hamilton, J. Chem. Soc., Chem. Commun., 1991, 1767 DOI: 10.1039/C39910001767
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