Issue 22, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

[Ru4(CO)10(µ-CO)(µ4-PPh)(µ4-η2-PhNNPh)]: the first example of an azobenzene molecule coordinated on a square metal face

John F. Corrigan,   Simon Doherty,   Nicholas J. Taylor  and  Arthur J. Carty  

Abstract

Reaction of azobenzene, under photolytic conditions, with the 62-electron butterfly cluster [Ru4(CO)13(µ3-PPh)]1 affords the first example of a 64-electron square-planar cluster containing a coordinated azobenzene ligand; a single crystal X-ray analysis of [Ru4(CO)10(µ-CO)(µ4-PPh)(µ4-η2-PhNNPh)]2 has revealed a novel capped trigonal prismatic Ru4PN2 skeleton.

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Article information

DOI
https://doi.org/10.1039/C39910001640
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1640-1641

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[Ru4(CO)10(µ-CO)(µ4-PPh)(µ4-η2-PhNNPh)]: the first example of an azobenzene molecule coordinated on a square metal face

J. F. Corrigan, S. Doherty, N. J. Taylor and A. J. Carty, J. Chem. Soc., Chem. Commun., 1991, 1640 DOI: 10.1039/C39910001640

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