Issue 19, 1991

Molecular recognition of racemic phosphines by a chiral ruthenium porphyrin

Abstract

The preparation of ruthenium ‘picket-fence’ porphyrins bearing optically active α-methoxy-α-(trifluoromethyl)phenylacetyl residues on both sides of the porphyrin plane is described; chiral recognition in the complexation of racemic benzylmethylphenylphosphine to the α,β,α,β isomer leads to the formation of one of three possible product diastereoisomers with high stereoselectivity (>95%).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1350-1352

Molecular recognition of racemic phosphines by a chiral ruthenium porphyrin

P. Le Maux, H. Bahri and G. Simonneaux, J. Chem. Soc., Chem. Commun., 1991, 1350 DOI: 10.1039/C39910001350

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