The complex composed of nickel(II) and the optically active N,N′-diethylcyclohexane-1,2-diamine (chxn) showed ability to recognize the shape of molecules in terms of the configuration of the various OH groups in aldoses during the epimerization of D-glucose to D-mannose.
K. Hataya, R. Yanagihara, S. Osanai and S. Yoshikawa, J. Chem. Soc., Chem. Commun., 1991, 1246 DOI: 10.1039/C39910001246
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