Dihydrobenzazaphosphole oxides (e.g.6) are important products in the photochemical reactions of phosphinic azides having P-mesityl or P-(2,4,6,-triisopropylphenyl) groups, suggesting that PV nitrenes are not necessarily averse to intramolecular insertion.
M. J. P. Karger and P. A. Shimmin, J. Chem. Soc., Chem. Commun., 1991, 1187 DOI: 10.1039/C39910001187
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