The isolation of a 5-hydroperoxide which has been postulated as an initial intermediate in oxidative transformation of carota-1,4-dienes into 1,5-epidioxy derivatives was facilitated by using 14-acetoxycarota-1,4-diene 1c; the present results allowed us to substantiate the aspects for the autoxidation pathway in non-conjugated 1,4-diene systems.
Y. Hashidoko, S. Tahara and J. Mizutani, J. Chem. Soc., Chem. Commun., 1991, 1185 DOI: 10.1039/C39910001185
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