Cyanotrimethylsilane reacts with α,β-unsaturated ketones to afford 1,4- and 1,2-adducts regioselectively in the presence of strongly acidic montmorillonite and strongly basic CaO or MgO, respectively.
K. Higuchi, M. Onaka and Y. Izumi, J. Chem. Soc., Chem. Commun., 1991, 1035 DOI: 10.1039/C39910001035
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