Issue 13, 1991

Metallation of a crown thioether ligand. Synthesis, structure and reactivity of [Pt(L1)][BF4] and structure of [PtI2(L1)][BF4](L1= 2,6,10-trithia[11]-m-benezenophane)

Abstract

Metallation of L1 results in formation of the square-planar, crown thioether complex [Pt(L1)][BF4]1; the versatility of this S3C donor ligand is demonstrated by substitution for the central S donor and oxidative-addition to octahedral complexs of PtIV.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 893-895

Metallation of a crown thioether ligand. Synthesis, structure and reactivity of [Pt(L1)][BF4] and structure of [PtI2(L1)][BF4](L1= 2,6,10-trithia[11]-m-benezenophane)

G. S. Hanan, J. E. Kickham and S. J. Loeb, J. Chem. Soc., Chem. Commun., 1991, 893 DOI: 10.1039/C39910000893

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