Issue 13, 1991

Hydrogen loss from pentamethylcyclopentadienyl–ruthenium complexes; the synthesis and X-ray structure of [Ru(C5Me4CH2Cl)Cl3(Me2S)]

Abstract

Reaction of [{C5Me5RuCl2}2] with Me2SO (in air in CHCl3) gives [(C5Me4CH2)RuCl2(Me2SO)], 2a; this reacts with HCl to give [(C5Me4CH2Cl)RuCl3(Me2S)](also in high yield), characterised by an X-ray structure determination.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 883-884

Hydrogen loss from pentamethylcyclopentadienyl–ruthenium complexes; the synthesis and X-ray structure of [Ru(C5Me4CH2Cl)Cl3(Me2S)]

C. Wei, F. Aigbirhio, H. Adams, N. A. Bailey, P. D. Hempstead and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1991, 883 DOI: 10.1039/C39910000883

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