Alkenyl-, dienyl- and trienylidene-chromium and tungsten complexes (CO)5M![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
[C(OMe){CHCH-(CHCH)n-R}][n= 0, 1, 2] are produced in one step by photolysis of M(CO)6[M = Cr, W] in the presence of 2-propyn-1-ol derivatives H–C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CC(H)(OH)[(CHCH)n–R] and methanol.
H. Le Bozec, C. Cosset and P. H. Dixneuf, J. Chem. Soc., Chem. Commun., 1991, 881 DOI: 10.1039/C39910000881
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