An efficient 1,7-asymmetric induction was achieved with up to 82% diastereoisomeric excess (d.e.) in the diastereoselective reduction of the γ-keto ester 4 and o-acetylbenzoate 6 using the chiral podand 2 as chiral auxiliary.
Y. Tamai, S. Koike, A. Ogura and S. Miyano, J. Chem. Soc., Chem. Commun., 1991, 799 DOI: 10.1039/C39910000799
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