The metal-centred radical [(η5-C5H5)Cr(CO)3]· abstracts the halogen atoms from a number of alkyl, allyl and benzyl halides to form the halochromium compounds [(η5-C5H5)Cr(CO)3X](X = Br, I) and the corresponding carbon-centred radicals; the latter subsequently undergo a wide variety of coupling, atom abstraction and atom donation reactions.
C. A. Goulin, T. A. Huber, J. M. Nelson, D. H. Macartney and M. C. Baird, J. Chem. Soc., Chem. Commun., 1991, 798 DOI: 10.1039/C39910000798
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