Issue 11, 1991

The π and σ bonding modes of meso-octaethylporphyrinogen to transition metals: the X-ray structure of a meso-octaethylporphyrinogen–zirconiuml(IV) complex and of the parent meso-octaethylporphyrinogen ligand

Abstract

The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen–zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 790-792

The π and σ bonding modes of meso-octaethylporphyrinogen to transition metals: the X-ray structure of a meso-octaethylporphyrinogen–zirconiuml(IV) complex and of the parent meso-octaethylporphyrinogen ligand

D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun., 1991, 790 DOI: 10.1039/C39910000790

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