The meso-octaethylporphyrinogen tetraanion provides σ and π binding pyrrolyl anions to electron poor transition metals, as shown in the structure of the meso-octaethylporphyrinogen–zirconium(IV) complex containing two η5 and two σ metal-bonded pyrrolyl anions.
D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun., 1991, 790 DOI: 10.1039/C39910000790
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