Terminal alkynes are converted into (E)-1-cyanoalk-1-enes in good yields via hydroboration followed by reaction with copper(I) cyanide and copper(II) acetate in the presence of a small amount of water, in hexamethylphosphoric triamide.
Y. Masuda, M. Hoshi and A. Arase, J. Chem. Soc., Chem. Commun., 1991, 748 DOI: 10.1039/C39910000748
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