When laser-ablated and monitored by FTICR mass spectrometry, silver sulphide, selenide and telluride, and elemental mixtures of silver with selenium or tellurium, yield large silver chalcogenide cluster anions, including the series [Ag2n– 1En]–(E = S, Se, Te) with n⩽ 14.
J. Ei-Nakat, I. Dance, K. Fisher and G. Willet, J. Chem. Soc., Chem. Commun., 1991, 746 DOI: 10.1039/C39910000746
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