Issue 6, 1991

Stereocontrolled multiple functionalization of cycloheptadienoneiron complexes via enolate alkylation

Abstract

Alkylation of enolates from tricarbonyl(6-oxocycloheptadiene)iron occurs with complete stereoselectivity trans to the metal, while reduction of the ketone occurs with stereochemistry dictated by the boat conformation adopted by these molecules.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 394-396

Stereocontrolled multiple functionalization of cycloheptadienoneiron complexes via enolate alkylation

A. J. Pearson and K. Chang, J. Chem. Soc., Chem. Commun., 1991, 394 DOI: 10.1039/C39910000394

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