Issue 1, 1991

Oxygen atom transfer in dialkyldioxo-molybdenum or -tungsten complexes. A case of dialkyldioxo-alkylalkylideneoxohydroxometal tautomerism

Abstract

Reaction of bipyridylbis-2-(methylbenzyl)dioxomolybdenum or the tungsten analogue in solution, at room temperature, yields 2-methylbenzaldehyde and 2-methylbenzyl alcohol as the main products; their formation is rationalized in terms of a pseudo ‘keto–enol’ tautomeric equilibrium.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 55-56

Oxygen atom transfer in dialkyldioxo-molybdenum or -tungsten complexes. A case of dialkyldioxo-alkylalkylideneoxohydroxometal tautomerism

H. Arzoumanian, H. Krentzien and H. Teruel, J. Chem. Soc., Chem. Commun., 1991, 55 DOI: 10.1039/C39910000055

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