The thiocyanate group can bond via sulphur or nitrogen or bridge between two centres, but in diphenylantimony thiocyanate, unusual bridging gives antimony atoms coordinated by, respectively, two sulphur atoms, two nitrogen atoms and one atom of each type, allowing development of a curious infinite ‘triangular spiral’ structure in the solid state.
G. E. Forster, I. G. Southerington, M. J. Begley and D. B. Sowerby, J. Chem. Soc., Chem. Commun., 1991, 54 DOI: 10.1039/C39910000054
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...