The telluronium salts (1) and (2), precursors of the non-stabilized telluronium ylide, on treatment with organolithium reagents, reacted with aldehydes to afford secondary alcohols via tetraorganyl tellurium intermediates.
L. Shi, Z. Zhou and Y. Huang, J. Chem. Soc., Perkin Trans. 1, 1990, 2847 DOI: 10.1039/P19900002847
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