Issue 24, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Rational construction of mixed-metal alkoxides

Brian A. Vaartstra,   John C. Huffman,   William E. Streib  and  Kenneth G. Caulton  

Abstract

The acidic protons in Zr2(OR)8(ROH)2, R = Pri, serve as a controlled functionality and react with Ba metal and with LiNMe2 to give the hydrocarbon-soluble heterometallic alkoxides Ba2Zr4(OR)20 and LiZr2(OR)9(ROH) which have been characterized in solution by NMR spectroscopy and in the solid state by X-ray diffraction: Zr2(OR)9 units bind the Li+ and Ba2+via bridging alkoxides and, for Li+, a terminal alcohol ligand which hydrogen bonds to a terminal alkoxide on zirconium.

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Article information

DOI
https://doi.org/10.1039/C39900001750
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1750-1751

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Rational construction of mixed-metal alkoxides

B. A. Vaartstra, J. C. Huffman, W. E. Streib and K. G. Caulton, J. Chem. Soc., Chem. Commun., 1990, 1750 DOI: 10.1039/C39900001750

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