The enantioselective glyoxylate–ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.
M. Terada, K. Mikami and T. Nakai, J. Chem. Soc., Chem. Commun., 1990, 1623 DOI: 10.1039/C39900001623
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