From AlCl3 and Li[C(PMe2)(SiMe3)2] in a 1:2 stoichiometric ratio a novel heterocycle (Me)(Cl)A[graphic ommitted]Me24, exhibiting a number of unusual features, is obtained by methyl migration from silicon to aluminium.
H. H. Karsch, K. Zellner and G. Müller, J. Chem. Soc., Chem. Commun., 1990, 1621 DOI: 10.1039/C39900001621
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