Issue 20, 1990

Tritium NMR in conformational analysis: isotopic perturbation of the ring inversion equilibrium in [3H]cyclohexane

Abstract

Integration of the axial and equatorial tritium signals in the 3H NMR spectrum of [3H]cyclohexane at –88°C shows that tritium prefers the equatorial site by 11.2 ± 0.5 cal mol–1(1 cal = 4.184 J), in agreement with expectations based on previous NMR work with [2H]cyclohexane.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1427-1429

Tritium NMR in conformational analysis: isotopic perturbation of the ring inversion equilibrium in [3H]cyclohexane

F. A. L. Anet, D. J. O'Leary and P. G. Williams, J. Chem. Soc., Chem. Commun., 1990, 1427 DOI: 10.1039/C39900001427

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