The reversible thermal conversion of the fungal sesquiterpene Isovelleral (2) into (1) is a unique Intramolecular ene reaction proceeding via the bicyclic enol (3), which is demonstrated by kinetic studies, deuterium incorporation, and the trapping of (3).
T. Hansson, R. Bergman, O. Sterner and B. Wickberg, J. Chem. Soc., Chem. Commun., 1990, 1260 DOI: 10.1039/C39900001260
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