Issue 17, 1990

Low-temperature syntheses of polysilanes and polygermanes in diethyl ether

Abstract

Both soluble and insoluble polysilanes and an insoluble polygermane have been prepared in high yield and at moderate temperatures from the interactions of alkylaryl-, diaryl-, and dialkyl-dichlorosilanes and diphenyldichlorogermane with sodium sand in the presence of 1,4,7,10,13-pentaoxacyclopentadecane (15-crown-5) in refluxing diethyl ether.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1147-1148

Low-temperature syntheses of polysilanes and polygermanes in diethyl ether

R. H. Cragg, R. G. Jones, A. C. Swain and S. J. Webb, J. Chem. Soc., Chem. Commun., 1990, 1147 DOI: 10.1039/C39900001147

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements