The (–)-N-α-Methylbenzyl-3,5-dihydrodinaphthazepine–BH3 complex reduces aromatic ketones to alcohols with 11–57% enantiomeric excess (e.e.) in the presence of BF3·OEt2, the (–)-N-α-methylbenzyl-3,5 dihydrodinaphthazepine–BF3 complex catalyses asymmetric reduction of acetophenone by N,N′-diethylaniline–BH3 to give α-phenylethyl alcohol in 51% e.e.
J. V. B. Kanth and M. Periasamy, J. Chem. Soc., Chem. Commun., 1990, 1145 DOI: 10.1039/C39900001145
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