In the complex [Ph4P+]2[Cu{OC(CF3)2OH}4]2–, four-co-ordinate, square-planar Cu2+ lies at the centre of a 16-membered macrocycle held together by hydrogen-bonding between four fluorinated alkoxide ligands.
R. Hynes, N. C. Payne and C. J. Willis, J. Chem. Soc., Chem. Commun., 1990, 744 DOI: 10.1039/C39900000744
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