A small amount of water has been shown to be a precursor of an effective electrogenerated base via the formation of hydroxide ion, as revealed in the electroreductive alkylation of dialkyl phosphonates with alkyl halides.
M. Kimura, T. Yamashita, T. Kurata and Y. Sawaki, J. Chem. Soc., Chem. Commun., 1990, 259 DOI: 10.1039/C39900000259
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