Addition of aqueous KCl to the reaction of diphenylethyne and mercury(II) acetate in methanol induces an unprecedented geminal double mercuration of the triple bond; the X-ray crystal structure of the product shows an unusually short Hg(1)–Hg(2) interatomic distance.
M. Bassetti and G. Bocelli, J. Chem. Soc., Chem. Commun., 1990, 257 DOI: 10.1039/C39900000257
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