The X-ray structure of cis-bis(2,6-diphenylpyridinato-N, C2′)platinum(II) shows the first example of helical chirality for a ‘square planar’ co-ordination compound with nonchiral ligands; 1H NMR investigations indicate no racemization of the compound in solution on the NMR time scale.
C. Deuschel-Cornioley, H. Stoeckli-Evans and A. von Zelewsky, J. Chem. Soc., Chem. Commun., 1990, 121 DOI: 10.1039/C39900000121
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