Issue 2, 1990

Metathesis polymerization of 7-oxa-2,3-bismethoxycarbonylbicyclo[2.2.1]hepta-2,5-diene: synthesis of novel conjugated polyenes

Abstract

Novel high-molecular-weight polymers are readily made by the alkene metathesis reaction using 7-oxa-2,3-bismethoxycarbonylbicyclo[2.2.1]hepta-2,5-diene as the monomer and Ru and Os chlorides as catalysts; these polymers are readily dehydrogenated using dichlorodicyanobenzoquinone to afford novel purple–red conjugated polyenes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 119-121

Metathesis polymerization of 7-oxa-2,3-bismethoxycarbonylbicyclo[2.2.1]hepta-2,5-diene: synthesis of novel conjugated polyenes

J. G. Hamilton, D. G. Marquess, T. J. O'Neill and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1990, 119 DOI: 10.1039/C39900000119

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