Eight- and nine-membered rings are available by using a combined annulation–ring cleavage strategy which utilises the reaction of the stannane (1) or the allylsilane (7) with silylated enediois and ring opening of the thus formed bicyclic diols.
T. V. Lee, F. S. Roden and J. R. Porter, J. Chem. Soc., Perkin Trans. 1, 1989, 2139 DOI: 10.1039/P19890002139
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