Issue 11, 1989

An unusual base-catalysed rearrangement of an α-ethoxycarbonylethyl (or α-cyanoethyl) cyclic β-keto ester

Abstract

Treatment of the title compounds (3), (7), and (8) with potassium t-butoxide afforded the unusual rearrangement products (5), (9), and (10).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 2137-2139

An unusual base-catalysed rearrangement of an α-ethoxycarbonylethyl (or α-cyanoethyl) cyclic β-keto ester

Z. Xie, I. Nakamura, H. Suemune and K. Sakai, J. Chem. Soc., Perkin Trans. 1, 1989, 2137 DOI: 10.1039/P19890002137

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