Issue 10, 1989

Lack of secondary β-deuterium kinetic isotope effect in the solvolysis of 2-chloro-2,6,10-trimethyldodeca-6,10-diene. Indication of extended Π-participation

Abstract

The title compound (3) with two deuteriated methyl groups attached to the reaction centre undergoes solvolysis without a kinetic isotope effect indicating participation of both double bonds.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1989, 1861-1861

Lack of secondary β-deuterium kinetic isotope effect in the solvolysis of 2-chloro-2,6,10-trimethyldodeca-6,10-diene. Indication of extended Π-participation

S. Borčić, K. Humski, V. Imper, O. Kronja, M. Orlović and E. Polla, J. Chem. Soc., Perkin Trans. 1, 1989, 1861 DOI: 10.1039/P19890001861

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