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Issue 2, 1989
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A bent mixed-valence manganese(III/II/III) complex: a new class of trinuclear, acetate bridged Schiff's base compounds exhibiting a g= 2 multiline e.s.r. signal

Abstract

The e.s.r. spectrum of the bent mixed valence Mn(III/II/III)(saladhp)2(OAc)4(MeOH)2[saladhp = 2-(salicylideneaminato)- 1,3-dihydroxy-2-methylpropane] in dimethylformamide provides the observation of a multiline e.s.r. signal from a trinuclear mixed-valence manganese complex and allows for the comparison of magnetic and spectroscopic properties of related models for the photosynthetic water oxidizing enzyme.

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Article type: Paper
DOI: 10.1039/C39890000084
Citation: J. Chem. Soc., Chem. Commun., 1989,0, 84-86
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    A bent mixed-valence manganese(III/II/III) complex: a new class of trinuclear, acetate bridged Schiff's base compounds exhibiting a g= 2 multiline e.s.r. signal

    D. P. Kessissoglou, M. L. Kirk, C. A. Bender, M. S. Lah and V. L. Pecoraro, J. Chem. Soc., Chem. Commun., 1989, 0, 84
    DOI: 10.1039/C39890000084

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