Issue 2, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

η2-S,S′-1,5-dithia-2,4,6,8-tetrazocine analogues of η2-alkene complexes: preparation and electronic structure of Pt[1,5-(Me2N)2C2N4S2](PPh3)2

Tristram Chivers,   Kaveripatnam S. Dhathathreyan  and  Tom Ziegler  

Abstract

The reaction of Pt(C2H4)(PPh3)2 with 1,5-E2N4S2(E = Ph2P, Me2NC) in acetonitrile produces high yields of Pt(1,5-E2N4S2)(PPh3)2 in which the η2-S,S′ bonding between platinum and the heterocyclic ligand is shown by density functional calculations to be analogous to that found in η2-alkene-platinum complexes.

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Article information

DOI
https://doi.org/10.1039/C39890000086
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 86-88

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η2-S,S′-1,5-dithia-2,4,6,8-tetrazocine analogues of η2-alkene complexes: preparation and electronic structure of Pt[1,5-(Me2N)2C2N4S2](PPh3)2

T. Chivers, K. S. Dhathathreyan and T. Ziegler, J. Chem. Soc., Chem. Commun., 1989, 86 DOI: 10.1039/C39890000086

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