Issue 22, 1989

Catalytic dehydrosilylation of 1-trimethylsilyloxycyclopent-1-ene into cyclopent-2-enone with oxygen over palladium supported on silica

Abstract

1-Trimethylsilyloxycylopent-1-ene can be catalytically converted to cyclopent-2-enone by its reaction with oxygen in the presence of palladium supported on silica, which gave the 90.1% yield of cyclopent-2-one and the 99.2% selectivity at 333 K for 24 h.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1697-1699

Catalytic dehydrosilylation of 1-trimethylsilyloxycyclopent-1-ene into cyclopent-2-enone with oxygen over palladium supported on silica

T. Baba, K. Nakano, S. Nishiyama, S. Tsuruya and M. Masai, J. Chem. Soc., Chem. Commun., 1989, 1697 DOI: 10.1039/C39890001697

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