Issue 19, 1989

AlCl3-mediated regioselective migration of a methoxy group of N-methoxy-N-phenylamides to the ortho position of the phenyl ring

Abstract

AlCl3-mediated decomposition of N-methoxy-N-phenylamides in dichloroethane leads to regioselective intramolecular migration of the methoxy group from the nitrogen to the ortho position of the phenyl ring via a tight ion pair intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1450-1451

AlCl3-mediated regioselective migration of a methoxy group of N-methoxy-N-phenylamides to the ortho position of the phenyl ring

Y. Kikugawa and M. Shimada, J. Chem. Soc., Chem. Commun., 1989, 1450 DOI: 10.1039/C39890001450

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