The complex [Ru2(CO)(CH2![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2)(µ-CH2)(µ-CO)(η-C5H5)2] undergoes methylene–ethylene combination on heating to give propene, and ethylene activation upon oxidation with Ag+ to give the µ-vinyl cation [Ru2(CO)2(µ-CHCH2)(µ-CH2)(η-C5H5)2]+; treatment of the latter with H– affords [Ru2(CO)2(µ-CH2)(µ-CHCH3)(η-C5H5)2], which evolves propene more efficiently on heating.
N. M. Doherty, J. A. K. Howard, S. A. R. Knox, N. J. Terrill and M. I. Yates, J. Chem. Soc., Chem. Commun., 1989, 638 DOI: 10.1039/C39890000638
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