Issue 6, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and structure of a technetium nitride cation and tetrabromotechnetate(II) anion in [TcBr(N)(bipy)2]2[TcBr4](bipy = 2,2′-bipyridyl)

Colin M. Archer,   Jonathan R. Dilworth,   J. Duncan Kelly  and  Mary McPartlin  

Abstract

Reaction of [TcNBr4]– with excess of 2,2′-bipyridyl (bipy) in methanol gives cis-[TcBr(N)(bipy)2]+; in ethanol the same cation is generated together with the novel tetrahedral TcII tetrabromo anion [TcBr4]2–.

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Article information

DOI
https://doi.org/10.1039/C39890000375
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 375-376

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The synthesis and structure of a technetium nitride cation and tetrabromotechnetate(II) anion in [TcBr(N)(bipy)2]2[TcBr4](bipy = 2,2′-bipyridyl)

C. M. Archer, J. R. Dilworth, J. D. Kelly and M. McPartlin, J. Chem. Soc., Chem. Commun., 1989, 375 DOI: 10.1039/C39890000375

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