Issue 6, 1989

Monomeric phosphinoboranes: the role of the B- and P-substituents for P[double bond, length half m-dash]B multiple bonding

Abstract

The influence of the boron substituents on the structures of the first fully characterized monomeric diphosphinoboranes [(2,4,6-Me3C6H2)2P]B–X (X = OEt, Br) has been established; especially for X = Br, P–B multiple bonding may be clearly inferred from the molecular structure.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 373-375

Monomeric phosphinoboranes: the role of the B- and P-substituents for P[double bond, length half m-dash]B multiple bonding

H. H. Karsch, G. Hanika, B. Huber, K. Meindl, S. König, C. Krüger and G. Müller, J. Chem. Soc., Chem. Commun., 1989, 373 DOI: 10.1039/C39890000373

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