Substituted 2,5-dihydrothiophene S,S-dioxides, which are stable precursors of the corresponding buta-1,3-dienes, were prepared via reactions of 3-methylene-2,3-dihydrothiophene S,S-dioxide with electrophiles and nucleophiles; this method was applied to the synthesis of (±)-ipsenol.
T. Nomoto and H. Takayama, J. Chem. Soc., Chem. Commun., 1989, 295 DOI: 10.1039/C39890000295
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