The activation energy of reaction of metal co-ordinated allylic alkenes to cationic metal-allyls has been measured and follows the prediction of Marcus theory for electron transfer indicative of an initial electron transfer dominating the kinetics of the reaction.
R. H. Hill, J. Chem. Soc., Chem. Commun., 1989, 293 DOI: 10.1039/C39890000293
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