Issue 2, 1989

Fluoride ion mediated peterson alkenation of bis(trimethylsilyl)methylimines: a novel synthesis of 2-aza-1,3-dienes and N-vinyl-β-lactams

Abstract

The formation of bis(trimethylsily)methylimines and their transformation into aza-1,3-dienes by means of a fluoride-induced catalytic Peterson alkenation is reported; when the procedure was applied to N-[bis(trimethylsilyl)methyl]-azetidin-2-ones, a wide range of N-vinyl derivatives were obtained in high yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 72-74

Fluoride ion mediated peterson alkenation of bis(trimethylsilyl)methylimines: a novel synthesis of 2-aza-1,3-dienes and N-vinyl-β-lactams

J. Lasarte, C. Palomo, J. P. Picard, J. Dunogues and J. M. Aizpurua, J. Chem. Soc., Chem. Commun., 1989, 72 DOI: 10.1039/C39890000072

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