Cerium(IV) induces electron transfer in penta-ammineoxaloacetatocobalt(III) perchlorate, yielding CO2 and cobalt(II) quantitatively as ultimate products due to carbon–carbon bond fission. Enzymatic decarboxylation of oxaloacetic acid yields only pyruvic acid, whereas cerium(IV) oxidises oxaloacetic acid to CO2, probably because of radical intervention.
K. Subramani and V. S. Srinivasan, J. Chem. Soc., Dalton Trans., 1988, 1413 DOI: 10.1039/DT9880001413
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