Homochiral 6-methoxy substituted cyclohexadienyltricarbonyliron complexes have been obtained by complexation of the dimethyl ether of 1-methylcyclohexa-1,3-diene-5,6-diol (available via microbial oxidation of toluene) and demethoxylation with triphenylcarbenium tetrafluoroborate.
P. W. Howard, G. R. Stephenson and S. C. Taylor, J. Chem. Soc., Chem. Commun., 1988, 1603 DOI: 10.1039/C39880001603
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