Issue 24, 1988

Imino Diels–Alder reaction of 2-t-butyldimethylsilyloxycyclohexadiene: isolation of an azabicyclo[2.2.2]octene silyl enol ether adduct

Abstract

The imino Diels–Alder reaction of (1) with 2-t-butyldimethylsilyloxycyclohexadiene (2) gave after acidic work-up mainly the bicyclic enol ethers (5a)(for which a novel X-ray crystal structure determination is reported) and (5b) together with small amounts of bicyclic ketones (3a,b) and cyclohexenones (4a,b).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1601-1602

Imino Diels–Alder reaction of 2-t-butyldimethylsilyloxycyclohexadiene: isolation of an azabicyclo[2.2.2]octene silyl enol ether adduct

T. N. Birkinshaw, A. B. Tabor, A. B. Holmes and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1988, 1601 DOI: 10.1039/C39880001601

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